A series of poly[2-(2,6-dimethylpyran-4-ylidene)malononitrile-alt-1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PM-PPV), poly[2-{2,6- Bis-[2-(5-bromothiophen-2-yl)-vinyl]-pyran-4-ylidene}-malononitrile-alt-1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PMT-PPV) and poly[2-[2,6-Bis-(2-{4-[(4-bromophenyl)-phenylamino]-phenyl}-vinyl)-pyran-4-ylidene]-malononitrile-alt-1,4-bis(dodecyloxy)- 2,5-divinylbenzene] (PMTPA-PPV) were synthesized by the Heck coupling reaction. The band gap of PM-PPV, PMT-PPV and PMTPA-PPV were 2.18 eV, 1.90 eV and 2.07 eV, respectively. The LUMO energy levels of PM-PPV, PMT-PPV and PMTPA-PPV were 3.65 eV, 3.54 eV and 3.62 eV, respectively and the HOMO energy levels of those were 5.83 eV, 5.61 eV and 5.52 eV, respectively. The photovoltaic devices based on the polymers was fabricated. The efficiency of the solar cells based on PM-PPV, PMT-PPV and PMTPA-PPV were 0.028%, 0.031% and 0.11%, respectively and the open circuit voltage (Voc) was 0.59 V∼0.69 V under AM 1.5 G and 1 sun condition (100 mA/㎠).

Heck coupling reaction을 이용해서 poly[2-(2,6-dimethylpyran-4-ylidene)malononitrile-alt-1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PM-PPV), poly[2-{2,6-Bis-[2-(5-bromothiophen-2-yl)-vinyl]-pyran-4-ylidene}-malononitrile-alt-1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PMT-PPV), poly[2-[2,6-Bis-(2-{4-[(4-bromophenyl)-phenylamino]-phenyl}-vinyl)-pyran-4-ylidene]-malononitrile-alt- 1,4-bis(dodecyloxy)-2,5-divinylbenzene] (PMTPA-PPV)를 합성하였다. PM-PPV, PMT-PPV, PMTPA-PPV의 band gap은 각각 2.18 eV, 1.90 eV, 2.07 eV로 나타났다. LUMO 에너지 준위는 각각 3.65 eV, 3.54 eV, 3.62 eV로 나타났고 HOMO 에너지 준위는 각각 5.83 eV, 5.61 eV, 5.52 eV이고 소자를 제작하여 측정한 결과는 AM 1.5 G [1 sun condition (100 mA/㎠)]에서의 효율은 0.028%, 0.031%, 0.11%이고 open-circuit voltage (Voc)는 0.59 V∼0.69 V로 나타났다.