This study focuses on optimizing the reaction conditions for selectively oxidizing benzyl alcohol to benzaldehyde through a cost-effective and environmentally friendly electrochemical anodic oxidation process. To minimize the formation of cyanomethylation byproducts (3-phenyl-3-hydroxypropanenitrile), previously observed under constant voltage conditions (1.9 V), a constant current method (3 mA/cm2) was introduced. After a 16-hour reaction, a complete conversion (100%) of benzyl alcohol was achieved, yielding benzaldehyde as the main product, along with approximately 9% benzoic acid byproduct and a small amount of TBAP-related impurities. Additionally, experiments were conducted by replacing TBAP with TBAN as the electrolyte to reduce impurity formation; the advantages of the usage of TBAN are discussed.