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ISSN : 1225-0112(Print)
ISSN : 2288-4505(Online)
Applied Chemistry for Engineering Vol.35 No.6 pp.522-529
DOI : https://doi.org/10.14478/ace.2024.1061

Degradation Study of Lithium-Ion Batteries Using Lithium Plating/Stripping Model

Dong Hyup Jeon, Hye Kyoung Kim*, Hyeon Chan Seong**, Sichoon Moon***, Hyungjin Lee***
Department of Automotive Materials and Components Engineering, Dongguk University, Gyeongju, 38066, Republic of Korea
*Gyeongbuk Woman’s Policy Development Institute, Gumi 36849, Republic of Korea
**Korea Industrial Complex Cooperation, Gumi 39268, Republic of Korea
***Orange-I Co. Ltd., Seongnam 13486, Republic of Korea

Abstract

We predicted the degradation and long-term cycle life of lithium-ion batteries using an electrochemical-based lithium plating/ stripping model. We did not consider the complex degradation mechanism of lithium-ion batteries; we only applied the lithium plating/stripping model to perform numerical analysis and calculated the capacity fade during cycling, loss of lithium inventory, and charge/discharge performance. The results showed that a higher capacity fade was observed at lower temperatures, higher C-rates, and higher lithium plating kinetic rates. In addition, the more aged cell tended to be the greater the initial voltage increase during charging, and the shorter the charging time in CC mode.

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